solimeister.blogg.se - Reactivity of carboxylic acid derivatives

Reactivity of carboxylic acid derivatives free#

Esters (and Lactones) + H2O -> ? (acid-catalyzed vs.Relative Reactivities of Carboxylic Acid DerivativesĢ0-9 - Hydrolysis Reactions (Addition of H2O).Tetrahedral Intermediates, Reaction Rates, and Relative Stabilities.The Mechanism of Acyl Substitution Reactions Under Acidic Conditions.The Mechanism of Acyl Substitution Reactions Under Basic Conditions.

use pKa values to predict leaving group ability.

IR Spectroscopy of Acid Anhydrides (asymmetric stretch & symmetric stretch)Ģ0-8 - Reactions of Carboxylic Acid Derivatives (BIG TOPIC) – thru p.20-26 rationalise the relative reactivity of carboxylic acid derivatives towards nucleophilic attack.

Esters Prefer to be Planar (Z-conformation vs.

Substituents (“Branches”)Ģ0-5 - Structures, Properties, & Spectrosopy of Carboxylic Acid Derivatives

Esters: Straight-Chained Esters and Cyclic Esters (“Lactones”)Ģ0-5 - Priority Order of Principle Groups in Carboxylic Acid Derivatives.

SECTION 20 – Carboxylic Acid Derivatives and Nucleophilic Acyl Substitution ReactionsĢ0-1 - General Classes and Nomenclature of Carboxylic Acid Derivatives Salt Formation Because of their enhanced acidity, carboxylic acids react with bases to form ionic salts, as shown in the following equations.

Reactivity of carboxylic acid derivatives free#

3 - Chemical Quantities and StoichiometryĤ - Types of Chemical Reactions and Solution Stoichiometryħ - Quantum Mechanical View of the Atom, and Periodicityĩ - Covalent Bonding and Molecular Orbitalsġ0 - Liquids, Solids, and Intermolecular Forcesġ5 - Applications of Acid-Base Equilibriaġ6 - Spontaneity, Entropy, and Free Energyġ8 - Transition Metals and Coordination ChemistryĢ0 - An Introduction to Organic Chemistryġ - Structural, Bonding, Molecular PropertiesĢ - The Nature of Organic Compounds: Alkanes and Cycloalkanesģ - Stereochemistry of Alkanes and Cycloalkanes: 3-D Structures of MoleculesĤ - The Study of Organic Reactions: An Overviewġ0 - Substitution (SN2, SN1) and Elimination (E2, E1) Reactionsġ1 - Mass Spectrometry and IR Spectroscopyġ3 - Conjugated Systems and UV Spectroscopyġ5 - Electrophilic Aromatic Substitution (E.A.S.)ġ8 - Aldehydes and Ketones: Nucleophilic Addition ReactionsĢ0 - Carboxylic Acid Derivatives and Nucleophilic Acyl Substitution ReactionsĢ1 - Carbonyl Alpha-Substitution ReactionsĬarboxylic Acid Derivatives and Nucleophilic Acyl Substitution Reactions - Section 20 of Organic Chemistry Notes is 27 pages in length (page 20-1 through page 20-27) and covers ALL you'll need to know on the following lecture/book topics: